TitaniumTitanium
is a metal which is rarely used in the elemental form; titanium is
often alloyed with vanadium and aluminium to increase strength and
form high temperature corrosion resistant alloys. Titanium can
form
oxides, nitrides and hydrides; titanium oxide and titanium
nitride have uses in a wide range
of applications. Titanium
dioxide, due to its high stability and low toxicity
is
frequently used as a
paint pigment
and used in a range of
cosmetics.
Titanium nitride, due to
its high
stability and high hardness
is
frequently used as a
hard wearing
coating which can be
applied to
a range of abrasives
to prolong
life and improve cutting performance.
The extraction and
refining process for titanium is an energy intensive operation, hence
a high proportion of the costs associated with titanium is based on
the refining process as titanium chloride (one of the refined steps
in the manufacture of titanium metal) is reduced using magnesium
metal.
Although titanium is an incredibly stable metal at room
temperature and even under a wide range of corrosive environments, at
elevated temperatures titanium can be very reactive; for example for
CP (commercial purity) titanium above ~800C titanium can dissolve
it's own oxide! This is incredibly useful for diffusion bonding
titanium components together. The process of diffusion bonding is a
thermally driven process where atoms movement can move between two
titanium components which results in a strong bond between components
after cooling the components. The atmosphere around the diffusion
bonding process for titanium is tightly controlled, normally a good
vacuum to prevent nitrides, oxides or hydrides from forming. Another
great property of titanium is the ability for superplastic forming at
elevated temperatures, this is where titanium can be formed into
shapes requiring a high degree of strain to form the final component.
Since superplastic forming also relies of diffusion, for titanium it
can be beneficial to have a small amount of amount of hydrogen
present to favour the beta phase (which is one of the
crystallographic phases for titanium) this beta phase allows for
easier atom mobility and reduces the stress required for deformation.
Once the deforming operation is complete, the hydrogen level is
reduced using by vacuum at elevated temperature. If too much hydrogen
is added then hydrogen embittlement can occur and during forming
operations cracking occurs.
| Properties
of Titanium Metal Density 4.506 g/cm3 Melting point: 1668 °C Crystal Structure: HCP Youngs Modulus ~116 GPa Uses: Light weight structual, chemical inert metal |
Properties
of Titanium Dioxide Density 4.23 g/cm3 Melting point: 1843 °C Crystal Structure: Tetragonal Appearance: White solid (insoluble in water) Uses: White pigment used in paint and white LED's |
| Properties
of Titanium Nitride Density 5.22 g/cm3 Melting point: 2930 °C Hardness: 2400 (vickers) Crystal Structure: Appearance: White solid (insoluble in water) Uses: Hard ware resistant coating |
Properties
of Titanium Hydride Density 3.76 g/cm3 Hydrogen released ~300 °C Crystal Structure: Depends on which hydride phase is present Uses: Hydrogen storage material |
This video is a demonstration showing some of the characteristic properties associated with titanium |